El empleo de las radiaciones ionizantes y no ionizantes en el tratamiento de aguas residuales contaminadas con benzodiacepinas
Issue | Vol. 5 Núm. 1 (2022): Ciencia, Ambiente y Clima |
DOI | |
Publicado | jun 30, 2022 |
Estadísticas |
Resumen
En el presente trabajo se realizó una búsqueda bibliográfica sobre la presencia de las benzodiacepinas en las aguas residuales y potables, debido a la ineficiencia de las plantas de tratamiento de residuales líquidos, y sus posibles incidencias en los organismos acuáticos. Por otra parte, se estudió el empleo de tres procesos avanzados de oxidación (PAOs) (radiación UV, ultrasonido de alta frecuencia y la radiación gamma) y su combinación con los agentes oxidantes H2O2 y el reactivo de Fenton para la degradación de los fármacos de tipo benzodiacepínico, haciendo un especial énfasis en el diazepam y el midazolam. Se reportaron niveles de notificación en los cuerpos de agua desde 9,5 ng L-1 hasta 1 μg L-1. De los PAO estudiados, el más empleado fue la radiación UV, con un 90-100 % de degradación a las dos horas de tratamiento. El ultrasonido de alta frecuencia fue el proceso menos empleado en la degradación de las benzodiacepinas. En el caso de la radiación gamma, a pesar de sus elevados porcentajes de degradación a dosis entre 2500 Gy y 5000 Gy, el uso de este proceso ha sido limitado por las regulaciones que implican. Para los tres PAOs en estudio, su combinación con los agentes oxidantes H2O2 y el reactivo de Fenton supuso una mejora significativa en la eficiencia de degradación para los fármacos pertenecientes a la familia de las benzodiacepinas.
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Afiliaciones
Michel Manduca Artiles
Instituto Superior de Tecnologías y Ciencias Aplicadas (InSTEC.) La Habana, Cuba
Sarra Gaspard
Universidad de las Antillas, Pointe à Pitre Cedex, Guadeloupe
Ulises Javier Jáuregui-Haza
Instituto Tecnológico de Santo Domingo (INTEC), República Dominicana